Science
Silicon Out, Graphene In?
Posted by Sean Fallon at 11:10 AM on March 25, 2008
Physicists at the University of Maryland have demonstrated that graphene, a single-atom-thick sheet of graphite, has a greater ability to conduct electricity than any other known material at room temperature. In fact, electrons can travel up to 100 times faster in graphine than silicon, making it a likely candidate to replace it as a semiconductor material in devices like computer chips and sensors.
Graphene also has a resistivity (opposition to the flow of electric current) of 1.0 microOhm-cm—which is 35% less than copper. That figure would also make graphene the lowest resistivity material at room temperature. However, impurities in graphine make it less effective than copper at transferring electrons (at least for the moment). Still, with some refinement, the future looks promising for graphene as our next "miracle material." [University of Maryland via Slashdot]

Comments (AU Comments · US Comments)
There are currently no AU comments for this post.
Mio
Posted 3:38 PM 25/3/08
@Whoopsi: Yeah, wouldn't ballistic transfer come from kinetic theory, and not QM?
Mio
GiltProto
Posted 3:38 PM 25/3/08
Well if you want to make good Field Effect Transistors (FET) you'd like to have as close to a current sheet to form your transistor channel as possible. That means a very thin layer of highly conductive material, hey, just like this stuff! In an implanted GaAs MESFET the transistor channel is rather deep as compared to something like a pHEMT transistor which has a thin layer defined by a flat semiconductor junction and is pretty much the fastest type of FET available right now. Anyway, to make a transistor out of the graphene all you would really need is a teeny sheet of the stuff with two conductively attached electrodes on two sides of the sheet. You also need a third terminal (the gate) which would be connected to a small conductor that would lay over the channel insulated from it by a thin layer or layers of some insulator material. And there you have it, a small FET (probably more like a MOSFET) that can switch puny amounts of current very quickly. You could dope the graphene if you wanted to just to tweak the performance. I don't know why I know this stuff.
GiltProto
Whoopsi
Posted 3:38 PM 25/3/08
There is something a bit off about the claim that it "holds great promise for replacing conventional semiconductor materials such as silicon". Just because it has lower resistivity doesn't mean it's a better candidate. Take for example GaAs, it has higher electron mobility... and although it looked like the next silicon, it lacked serveral characteristics (Read [en.wikipedia.org] advantages/disadvantages of GaAs compared to Silicon). Not to diminish the achievement of the research, but it always annoys me to hear so many people talking about replacing silicon.
Perhaps there is a material (or more likely a technology) that will put silicon "out", but to base that on a single feature... such as low resistivity is a bit unwarranted. The biggest hurdle will always be fabrication/cost... but placing that aside, a quick search couldn't find anything on hole mobility (although I would assume it to be quite high), as well as the fact that there isn't a natural insulator, or dopants.
I'll preface this by saying I don't know too much about the subject, but I don't see how this material can be anything more than the connections between transistors. Advancements in interconnects (there is definitely a better word) is, however, an important area of research as the cross section gets smaller and smaller the resistance increases and a material such as this seems to be highly beneficial assuming it was integrated well.
In any case I didn't want to ramble for so long, but the title (and the original article) just rubbed me the wrong way. I think there is a reason they didn't make this claim in the Nanotechnology paper they wrote.
@ wikkit, I believe that ideally, graphene exhibits ballistic transfer, or at least only for short (i.e. ~500 nm) distances. Ballistic I believe means that mean free path of the electrons is longer than the distance it needs to travel... hence if the distance is only 500 nm, then the electrons won't be bouncing around but will travel directly and unhindered. I don't believe ballistic transfer is a quantum effect, and it doesn't mean the electron magically appears at the other end (where ever that is) instantly. Overall ballistic transfer means lower resistance. But currently Fuhrer states that the mobility is approximately 2 orders of magnitude less than the ideal case due to defects... and for ballistic conduction the material must be free of impurities ([en.wikipedia.org]).
Anyway, the more I look into it the more interesting it all is.
Whoopsi
pharago
Posted 3:38 PM 25/3/08
if they can build transistors and the like with this material, then its going to be pretty fast and cool and i mean cool in both senses
pharago
pdok
Posted 3:38 PM 25/3/08
I couldn't help but think what an unfortunate name for the professor.
pdok
wikkit
Posted 3:38 PM 25/3/08
@allenjnl
Graphene has a quantum effect called "ballistic transfer" where the electron that enters one end magically appears at the other end at the same instant. This is the kind of stuff that physicists and material scientists have wet dreams about.
wikkit
wikkit
Posted 3:38 PM 25/3/08
@allenjnl
Physics lesson:
There's a reason the speed of light is quoted as 'in a vacuum', anything (light, sound, electrons) slows down when it encounters matter. The electron still travels the same speed, but it gets scattered within the material, effectively slowing its speed.
wikkit
cyborgtroy
Posted 3:38 PM 25/3/08
Breasts* are made of silicone, which is a lot different from silicon.
Some of us, however, do not object to silicon breasts.
*non-edit fix: Real breasts are made of flesh. I'm of course referring to breast implants.
cyborgtroy
jkr
Posted 3:38 PM 25/3/08
so this is more cunductive and has less resistivity than other materials. ANybody else notice they are just saying the same thing twice. More conductive is the same thing as less resistivity. Clearly those writing the article have a firm grasp of these concepts. I have a black blanket, and it doesn't reflect light, and it absorbs light.
jkr
strider_mt2k
Posted 3:38 PM 25/3/08
Boron is a bigger buzz kill than Buzz Killington.
strider_mt2k
way_down_east
Posted 3:38 PM 25/3/08
Silicon is a semiconductor. You need conductors, semiconductors and insulators to make chips.
way_down_east
skittlzncombos
Posted 3:38 PM 25/3/08
But how will it look as breasts?
skittlzncombos
Chamellion
Posted 3:38 PM 25/3/08
I think what it means is that there is 100 times more resistence in silicon then in graphene
Chamellion
allenjnl
Posted 3:38 PM 25/3/08
100 times faster? I thought the speed of electrical flow was always 186,000 miles/sec. give or take. Maybe less resistance to current flow? Might be less electrons coming down the theoretical bobsled run, but they're all clocking pretty much the same E.T. on the same track. At least that's what I've always been told. WTF?
allenjnl
Molbork
Posted 3:38 PM 25/3/08
Stupid Boron messing up the party.
Molbork
BoinK
Posted 3:38 PM 25/3/08
For some reason this made me think of the time when you used a pencil (get it? GraphITe keke. Sweet jeebus I'm tired) to unlock the AMD Thunderbirds. Aaah memories.
BoinK
jibbly
Posted 5:49 PM 25/3/08
Nerdy talk going on up in here.
jibbly
vision646
Posted 5:49 PM 25/3/08
@allenjnl: Electrons travel through different materials at different speeds. This is mostly due to collisions with other atoms in the material (or by getting within the effective area of a charged partical) which deflect them in random directions. Thus it takes them longer to get from one end of the material to the other.
vision646
lynxminus
Posted 7:32 PM 25/3/08
Its good to see such a well thought out dissection of the issue here. As someone who has very little knowledge on the topic, it makes for an informative and entertaining read, a rare find these days.
lynxminus
TommyImages
Posted 7:32 PM 25/3/08
@allenjnl: I think he's talking about the drift velocity or Fermi velocity, hard to tell given the way the article is written.
TommyImages
MikeHinds
Posted 11:35 PM 25/3/08
@wikkit: and @allenjnl:
Electrons do not travel at the speed of light in a vacuum or anywhere else. Electrons are matter, not energy.
Light does travel at the speed of light, whether it's at visible light frequencies we know and love, higher (UV or X-ray), lower (IR or microwave), or much lower (radio/TV/etc). These are waves, (or energy particles for the quantum physicists), not matter particles such as electrons.
MikeHinds
wikkit
Posted 1:37 AM 26/3/08
@MikeHinds:
If light doesn't travel at the speed of light, someone really fubar'd the name. Besides, what happened to the wave-particle duality?
@Whoopsi:
Graphene is replacing carbon nanotubes as the futuristic material of choice for FET development because graphene is easier to handle/process. CNT's require sorting by size and conductivity. Both oxidize extremely easily though, and as you pointed out, there is no natural oxide as there is in silicon. It's a material that has massive promises, but is still in its infancy. If I remember correctly, the theoretical hole/electron mobilities are almost identical. The experimental values are orders of magnitude lower though. You'd have to look through some of the bigger science journals to get the juicy info.
wikkit
daveNYC
Posted 1:37 AM 26/3/08
Carbon is the most awesome element. Coal, diamonds, graphite, buckyballs, and nanotubes.
daveNYC
Geisrud
Posted 1:37 AM 26/3/08
All I'm saying is that it's all very "Tron-Esque"
Geisrud
Admiral Ackbar
Posted 3:38 AM 26/3/08
@MikeHinds:
Electrons don't carry the energy, the electromagnetic field does. What you're interested in is the speed of the field; which can by rule never be greater than the speed of light (obviously).
Admiral Ackbar
uberfu
Posted 3:38 AM 26/3/08
@cyborgtroy: silicon and silicone still come from the same source material_ They are merely refined to different specs_
Kind of like Diesel and Gasoline_ Both fuel - both come from the ssame source - just refined to different levels and used for different purposes_
But basiclly - yeah - silicon and silicone are both glass_
uberfu
bobvilla
Posted 3:38 AM 26/3/08
hey, the terps are good for something this year :)
bobvilla
pevans34
Posted 10:53 AM 26/3/08
Youve forgotten that to find the hypotenous one must add the square of both sides AND take the root of that result
pevans34
Terrorsaur.
Posted 5:25 PM 26/3/08
@pevans34:
ahaha. Genius.
Terrorsaur.
phor11
Posted 7:56 AM 27/3/08
@pevans34: but if you connect the hypotenuse' of two isosceles tringles, you're right back at "square" one...
phor11
phamou
Posted 7:56 AM 27/3/08
They should rename Sylicon Valley to Graphene Valley
phamou
tsukasa0002
Posted 3:08 PM 28/3/08
refer to the top of the page... boron, lol, research more into how processors are made... boron really messed the party up :(
tsukasa0002